Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? I cannot wrap my head around this. The relative decomposition temperatures are: MnSO4 755, FeSO4 537, CoSO4 708, NiSO4 675, CuSO4 598, ZnSO4 646, CdSO4 816, PbSO4 803, MgSO4 895, CaSO4 1149, and SrSO4 1374°C. Also, the solubility increases as we move … Thermal treatment of alkaline and alkaline earth metal sulphates on a graphite platform was performed over the temperature range 200–2000 °C. Thermal treatment of alkaline and alkaline earth metal sulphates on a graphite platform was performed over the temperature range 200–2000 °C. I cannot wrap my head around this. The solid residues produced at each temperature were located by scanning electron microscopy (SEM) and then identified by energy-dispersive (ED) X-ray spectroscopy and Raman microanalysis. Contrary to alkali metal sulphates, beryllium sulphate is water-soluble. MgO(s) + Fe/Si(s) → 2Mg(l) + Ca, Table 21.4 "Selected Properties of the Group 2 Elements", Table 21.3 "Selected Properties of the Group 1 Elements", Section 21.1 "Overview of Periodic Trends", Chapter 9 "Molecular Geometry and Covalent Bonding Models", Section 21.3 "The Alkali Metals (Group 1)", Section 24.5 "Common Classes of Organic Compounds", Figure 21.13 "Magnesium Alloys Are Lightweight and Corrosion Resistant", Table 17.1 "Solubility Products for Selected Ionic Substances at 25°C", Table 8.1 "Representative Calculated Lattice Energies", Section 12.6 "Bonding in Metals and Semiconductors", Chapter 8 "Ionic versus Covalent Bonding", Section 12.5 "Correlation between Bonding and the Properties of Solids", Chapter 7 "The Periodic Table and Periodic Trends", Chapter 25 "Appendix A: Standard Thermodynamic Quantities for Chemical Substances at 25°C". Arrange the following sulphates of alkaline earth metals in order of decreasing thermal stability. Their solubilities decrease on moving down the group from Be to Ba. Login. NaNO3 → Na2O + O2. By continuing you agree to the use of cookies. This paper is based on a dissertation submitted to the graduate College of the State University of Iowa by A. G. Ostroff, in partial fulfilment of the requirements for the Ph.D. degree. The alkaline earth metals burn in oxygen forming the ionic oxides of the type MO where M stands for alkaline earth metals except Sr, Ba, and Ra which form peroxides. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. Solubility and thermal stability of Oxo salts. These compounds are white solids and brown nitrogen dioxide and oxygen gases are also given off when heated. Solubility. In chemical terms, all of the alkaline earth metals react with the halogens to form the alkaline earth metal halides, all of which are ionic crystalline compounds (except for beryllium chloride, which is covalent). Vipin Sharma Biology Blogs for more information regarding every national level competitive exam in which biology is a part . (For more information on lattice energies, see (i) Nitrates Thermal stability. Why does the solubility of alkaline earth metal hydroxides in water increase down the group ? The more ionic the metal-oxygen bond the more basic the oxide is . Solubility and thermal stability of carbonates of alkaline earth metals increases on moving down the group due increase in the size of metal ions. The temperature at which its … However, carbonate of lithium, when heated, decomposes to form lithium oxide. The thermal stability of alkaline earth metal carbonates–MgCO3, CaCO3, SrCO3 and BaCO3, follows the order. Login. NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS Chauhan. Sulphates. Solubility decrease down the group from to. Arrange the following sulphates of alkaline earth metals in order of deceasing thermal stability; BeSO4, MgSO4, CaSO4, SrSO4 Arrange the alkaline earth metal carbonates in the decreasing order of thermal stability. ← Prev Question Next Question → Sulphates. The simple trend is true provided you include hydrated beryllium sulphate in it, but not if the beryllium sulphate is anhydrous. Arrange the alkaline earth metal carbonates in the decreasing order of thermal stability. MgSO 4 → MgO + SO 3. To be familiar with the reactions, compounds, and complexes of the alkaline earth metals. The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. Solubility of the Hydroxides. The sulphates of alkaline earth metal are prepared by the action of sulphuric acid on metals, metal oxides ,hydroxides and carbonates. Doubtnut is better on App . From Li to Cs, thermal stability of carbonates increases. solubility stability alkali-metals. Open App Continue with Mobile Browser. NCERT NCERT Exemplar NCERT Fingertips Errorless Vol-1 Errorless Vol-2. Remember. 10 views. NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS Chauhan. NCERT DC Pandey Sunil Batra HC Verma Pradeep Errorless. The sulphates of alkaline earth metal are prepared by the action of sulphuric acid on metals, metal oxides ,hydroxides and carbonates. U can like my Facebook page ie. Books. Books. Solubility of sulphates: The solubility of sulphates of alkaline earth metals decreases as we move down the group from Be to Ba due to the reason that ionic size increases down the group. The alkaline earth metals are all silver-colored and soft, and have relatively low densities, melting points, and boiling points. Copyright © 1959 Published by Elsevier Ltd. Journal of Inorganic and Nuclear Chemistry, https://doi.org/10.1016/0022-1902(59)80009-9. The outermost shell has electrons which experience lesser nuclear charge as the radius goes on increasing. asked Apr 30, 2019 in Chemistry by RenuK (68.1k points) kvpy; Welcome to Sarthaks eConnect: A unique platform where students can interact with teachers/experts/students to get solutions to their queries. Click here to get an answer to your question ️ Thermal stability of sulphates of alkaline earth metals increases down the group The thermal stability of alkaline earth metals increases down the group for hydroxides i-e., Be(OH)2 is less stable than Ba(OH)2. To neutralize excess stomach acid that causes indigestion, would you use BeCO. The sulphate of alkaline earth metals is less soluble. All the bicarbonates (except which exits in solution) exist … Ionic character and the thermal stability of the carbonates increases from Be to Ba. The soli… Thermal stability of alkali metal hydrides and carbonates (1 answer) Closed 1 year ago. Register; Test; Home; Q&A; Unanswered; Categories; Ask a Question; Learn ; Ask a Question. So, solubility should decrease from Li to Cs. Magnesium and calcium nitrates normally crystallize with water, and the solid may dissolve in its own water of crystallization to make a colorless solution before it starts to … The thermal stability of carbonates increases with the increasing basic strength of metal hydroxides on moving down the group.Thus the order is The bicarbonates of all the alkali metals are known. Present address: Magnolia Field Research Laboratories, Dallas, Texas, U.S.A. We use cookies to help provide and enhance our service and tailor content and ads. Open App Continue with Mobile Browser. The carbonates of alkali metals are stable towards heat. U can like my Facebook page ie. SrSO 4 Insoluble. (For more information on lattice energies, see NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS Chauhan. Physics. Thermal treatment of alkaline and alkaline earth metal sulphates on a graphite platform was performed over the temperature range 200–2000 °C. Thermal stability of alkali metal hydrides and carbonates (1 answer) Closed 1 year ago. Doubtnut is better on App. The sulphates, and are readily soluble and the solubility decreases from to . solubility: sulphates of alkali metals are soluble in water. Additional experiments involved the … Physics. Arrange the alkaline earth metal carbonates in the decreasing order of thermal stability. asked Dec 23, 2018 in S-Block Elements by monuk (68.0k points) s-block elements; neet; 0 votes. solubility: sulphates of alkali metals are soluble in water. The alkaline earth metals are all silver-colored and soft, and have relatively low densities, melting points, and boiling points. The salt containing one or more atoms of oxygen such as oxides ,hydroxides ,carbonate ,bicarbonate ,nitrite ,nitrate ,sulphates ,oxalates and phosphates are called oxo salts. Group 1 (a.k.a. Author has 1.8K answers and 3.1M answer views. The lattice energy remains constant because sulphate ion is so large, so that small change in cationic sizes do not make any difference. The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. Factors possibly influencing thermal stability of such salts are discussed, with special consideration of the effects of the metal's electronegativity and polarizing power on the condition of the anion. As a component of the alloy in an automotive spark plug electrode, would you use Be, Ca, or Ba? The thermal stability of sulphates increases with the increase in the size of cation and order is shown: Complex Compounds. 2LiNO3 → Li2O + 2NO2 + O2 2Ca (NO3)2→ 2CaO + 4NO2 + O2 . Sulphates of alkaline earth metals decompose on heating to give SO3 MSO 4 → MO + SO 3 The stability of sulphates of alkaline earth metals increases as the electropositive character of the metal increases. 2LiNO3 → Li2O + 2NO2 + O2 2Ca (NO3)2→ 2CaO + 4NO2 + O2 Sulphates: - The sulphates of both alkali and alkaline earth metals are thermally stable. Magnesium and calcium nitrates normally crystallize with water, and the solid may dissolve in its own water of crystallization to make a colorless solution before it starts to decompose. BeSO 4 Fairly soluble. Solubility of sulphates: The solubility of sulphates of alkaline earth metals decreases as we move down the group from Be to Ba due to the reason that ionic size increases down the group. Thermal stability. sulphate of Be and Mg are readily soluble in water. Thermal treatment of alkaline and alkaline earth metal sulphates on a graphite platform was performed over the temperature range 200–2000 °C. Thermal stability is increase with increase in the size of the cation and order is shown: Sulphates. 2Ca(NO 3) (s) 2CaO (s) + 4 NO 2(g) + O 2(g) As we move down group 1 and group 2, the thermal stability of nitrate increases. Group II metal hydroxides become more soluble in water as you go down the column. The solid residues produced at each temperature were located by scanning electron microscopy (SEM) and then identified by energy-dispersive (ED) X-ray spectroscopy and Raman microanalysis. The correct order of solubility of the sulphates of alkaline earth metals in water is . The soli… Nitrates of both group 1 and group 2 metals are soluble in water. Thermal treatment of alkaline and alkaline earth metal sulphates on a graphite platform was performed over the temperature range 200–2000 °C. The thermal decomposition of eleven (II) sulphates has been studied by a combination of thermogravimetric and differential thermal analysis. Among alkali metals Li 2 SO 4 decomposes like MgSO4 to give SO 3. Sulphates. BaSO 4 Insoluble. Thermal stability. Maths. Arrange the alkaline earth metal carbonates in the decreasing order of thermal stability. Biology . The Group 2 nitrates undergo thermal decomposition to the metal oxide, nitrogen dioxide and oxygen gas. 2Be + O 2 → 2BeO. Similar to lithium nitrate, alkaline earth metal nitrates also decompose to give oxides. The smaller size and the charge density increases the hydration energy of the beryllium sulphate leading to more solubility. BeSO 4: MgSO 4: CaSO 4: SrSO 4: 773 K: 1168 K: 1422 K: 1644 K . The Group 2 nitrates undergo thermal decomposition to the metal oxide, nitrogen dioxide and oxygen gas. As we move down group 1 and group 2, the thermal stability of nitrate increases. The salt containing one or more atoms of oxygen such as oxides ,hydroxides ,carbonate ,bicarbonate ,nitrite ,nitrate ,sulphates ,oxalates and phosphates are called oxo salts. Ba + O 2 → 2BaO Their solubilities decrease on moving down the group from Be to Ba. ← Prev Question Next Question → 0 votes . Thus the order: ← Prev Question Next Question → 0 votes .

As we move down group 1 and group 2, the thermal stability of nitrate increases. thermal stability is good for both alkali and alkaline earth metals. The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. Thanks for asking me. Chemistry. 1 answer. MgSO 4 Soluble. The solid residues produced at each temperature were located by scanning electron microscopy (SEM) and then identified by energy-dispersive (ED) X-ray spectroscopy and Raman microanalysis. Biology. The melts of alkali metal hydroxide—nitrate systems are thermally stable to at least 300°C above the melting temperatures. Salts of Oxoacids – Sulphates Sulphates of alkaline earth metals are white crystalline solids and thermally stable. LiNO3 and nitrates of alkaline earth metals on heating form their respective oxides NO2 and O2 . Owing to their higher lattice energies, the smallest alkaline earth metals should form the most stable oxides. `BeSO_(4), MgSO_(4), CaSO_(4), SrSO_(4)`. Sulphates of alkali metals are soluble in water. Why does the solubility of alkaline earth metal carbonates and sulphates in water decrease down the group ? Nitrates of alkali metals, except LiNO 3, decompose on strong heating to form nitrites.. LiNO 3, on decomposition, gives oxide.. Thermal decomposition of such compounds may well be a very complex process. Alkali metal sulphates are more soluble in water than alkaline earth metals. (i) Nitrates Thermal stability. As one moves from beryllium to barium thermal stability of carbonates usually increases. To describe how to isolate the alkaline earth metals. Among alkali metals Li 2 SO 4 decomposes like MgSO4 to give SO 3. Thermal stability of some metal sulphates. From Li to Cs, thermal stability of carbonates increases. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. The thermal stability of sulphates increases with the increase in the size of cation and order is shown: Complex Compounds. Solubility. The sulphates of alkaline earth metals are stable to heat . But, experimentally, order is reverse. Thermal treatment of alkaline and alkaline earth metal sulphates on a graphite platform was performed over the temperature range 200–2000 °C. Let’s try to make it systematic, so to speak. The sulphates of alkaline earth metals are stable to heat . From Li to Cs, due to larger ion size, hydration enthalpy decreases. NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS Chauhan. The correct order of the solubility of alkaline- earth metal sulphates in water is : The carbonates of alkali metals are stable towards heat. | EduRev NEET Question is disucussed on EduRev Study Group by … These compounds are white solids and brown nitrogen dioxide and oxygen gases are also given off when heated. Alkaline earth metals are also capable to form sulphates such as BeSO 4, and MgSO 4. Owing to their higher lattice energies, the smallest alkaline earth metals should form the most stable oxides. (For more information on solid electrolytes, see, drying agent for removing water from the atmosphere—CaCl, Group 2 elements almost exclusively form ionic compounds containing the M. How many liters of chlorine gas will be released at standard temperature and pressure? Physics. Additional experiments involved the … Paiye sabhi sawalon ka Video solution sirf photo khinch kar. Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals. 10 views. Sulphates of both group 1 and group 2 metals are stable towards heat. How many hours will it take to process the magnesium metal if a total current of 1.00 × 10. However, sulphates of alkaline earth metals show varied trends. Thus the order: Biology. Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy? Thermal stability of alkaline earth metal carbonates decreases in the order (A) BaCO3 > SrCO3 > CaCO3 > MgCO3 (B) BaCO3 > SrCO3 > MgCO3 > CaCO3 (C) Ca Click here to get an answer to your question ️ Thermal stability of sulphates of alkaline earth metals increases down the group With the increase in the cationic size on moving down the group, the extent of the hydration of the cation decreases.

, on decomposition, gives oxide.

Similar to lithium nitrate, alkaline earth metal nitrates also decompose to give oxides. Li 2 SO 4 → Li 2 O + SO 3. solubility stability alkali-metals. Similar to lithium nitrate, alkaline earth metal nitrates also decompose to give oxides. Thermal stability is increase with increase in the size of the cation and order is shown: Sulphates. The Nuffield Data Book quotes anyhydrous beryllium sulphate, BeSO 4 , as insoluble (I haven't been able to confirm this from any other source), whereas the hydrated form, BeSO 4 .4H 2 O is soluble. The thermal stability of alkaline earth metals increases down the group for hydroxides i-e., Be(OH)2 is less stable than Ba(OH)2. Peroxides are formed with increasing ease and increasing stability as the metal ions become larger. Carbonates of alkali metals are soluble in water with the exception of Li2CO 3. The solubility also increases down the group for these compounds i-e., Be(OH)2 is less soluble in water as compared to Ba(OH)2. Biology. This application involves reacting CO 2 with an alkaline earth oxide to form the carbonate, which is the reverse of the thermal decomposition reaction in which MCO 3 decomposes to CO 2 and the metal oxide MO (Equation 21.25). The sulphate of alkaline earth metals is less soluble. Similar to lithium nitrate, alkaline earth metal nitrates also decompose to give oxides. Maths. Arrange the following sulphates of alkaline earth metals in order of their decreasing thermal stability. Nitrates of alkali metals, except LiNO 3, decompose on strong heating to form nitrites.. LiNO 3, on decomposition, gives oxide.. Books. CaSO 4 Sparingly soluble. Copyright © 2021 Elsevier B.V. or its licensors or contributors. The lattice energy remains constant because sulphate ion is so large, so that small change in cationic sizes do not make any difference. (a) Nitrates (b) Carbonates (c) Sulphates. THE thermal stabilities of salts containing the same anion are well known to differ for different cations. Chemistry. Chemistry . But, experimentally, order is reverse. Vipin Sharma Biology Blogs for more information regarding every national level competitive exam in which biology is a part . Thermal stability of alkaline earth metal carbonates decreases in the order (A) BaCO3 > SrCO3 > CaCO3 > MgCO3 (B) BaCO3 > SrCO3 > MgCO3 > CaCO3 (C) Ca Chemistry. The sulphates, and are readily soluble and the solubility decreases from to . NCERT DC Pandey Sunil Batra HC Verma Pradeep Errorless. | EduRev NEET Question is disucussed on EduRev Study Group by … In chemical terms, all of the alkaline earth metals react with the halogens to form the alkaline earth metal halides, all of which are ionic crystalline compounds (except for beryllium chloride, which is covalent). Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. NaNO 3 → Na2O + O2. Jan 07,2021 - How does the thermal stability of hydroxide and sulphates of group 2 alkaline earth metals vary down the group ? The solubility of the alkaline earth's metal sulphates in water decreases in the sequence M g > C a > S r > B a. Alkali earth metals form solid carbonates. Stability: The sulphates of alkaline earth metal decompose on heating giving the oxides and SO 3. So, solubility should decrease from Li to Cs. For example, alkali metal salts such as sulptlates, carbonates, nitrates and perchlorates possess greater stability than the corresponding salts of less reactive metals, or the corresponding free acids. NCERT RD Sharma Cengage KC Sinha. Physics. The thermal stability of alkali and alkaline-earth metal hydroxide—nitrate systems has been investigated by thermal analysis, voltammetry and observation with a high-temperature microscope. Solubility. 2Ca + O 2 → 2CaO. The stability of sulphates of alkaline earth metals increases as the electropositive character of the metal increases. The sulphates become less soluble as you go down the Group. From Li to Cs, due to larger ion size, hydration enthalpy decreases. BeSO 4 , MgSO 4 , CaSO 4 , SrSO 4 SrSO 4 > CaSO 4 > Mg … LiNO3 and nitrates of alkaline earth metals on heating form their respective oxides NO2 and O2. 2Mg + O 2 → 2MgO. Arrange the following sulphates of alkaline earth metals in order of deceasing thermal stability; BeSO4, MgSO4, CaSO4, SrSO4 (ii) Carbonates. Remember. Thermal stability: - Carbonates: ... Nitrates: - Nitrates of alkali metal except Lithium nitrate on heating forms nitrites with the evolution of oxygen. The carbonates of alkaline earth metals also decompose on heating to form oxide and carbon dioxide. Case 1: As we go down the periodic group of alkaline earth metal, the size of atoms increase. All the alkaline earth carbonates will neutralize an acidic solution by, The alloy in a spark plug electrode must release electrons and promote their flow across the gap between the electrodes at high temperatures. Beryllium carbonate is unstable and should be kept in the atmosphere of CO 2. NCERT DC Pandey Sunil Batra HC Verma Pradeep Errorless. Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. Other alkali metal sulphates are stable to heat and do not decompose easily. Thermal stability. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. Gabriel Maria Ingo, Cristina Riccucci, Gianni Chiozzini, Origin of Gas Porosity in Gold‐Based Alloys Cast in Calcium Sulfate‐Bonded Investment and Influence of Metal Oxide Acid–Base Properties on Calcium Sulfate Thermal Stability, Journal of the American Ceramic Society, 10.1111/j.1151-2916.2001.tb00924.x, 84, 8, (1839-1843), (2004). 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Spark plug electrode, would you use Be, Ca, or Ba correct order of stability! ) carbonates ( 1 answer ) Closed 1 Year ago the more basic the is. For more information on lattice energies, the size of the metal ions become larger at! Change in cationic sizes do not make any difference stability of carbonates increases is increase with increase in decreasing. Anion are well known to differ for different cations heated, decomposes to form.... That causes indigestion, would you use BeCO soft, and boiling points polarized by combination! Or Ba these compounds are white solids and thermally stable also decompose to give oxides on lattice,... Oxide and carbon dioxide 1.00 × 10 of Be and Mg are soluble. Of eleven ( II ) sulphates has been studied by a small, highly cation. Solubility should decrease from Li to Cs MgSO4 to give so 3 become less soluble you... Are formed with increasing ease and increasing stability as the metal oxide, nitrogen dioxide and oxygen gases also! 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Can like my Facebook page ie sulphate leading to more solubility provided you include hydrated beryllium is., when heated hydration enthalpy decreases decomposes like MgSO4 to give oxides → Li 2 so decomposes! The column systematic, so that small change in cationic sizes do not make any difference on increasing not! Sulphate of Be and Mg are readily soluble and the solubility of alkaline earth is. Of the alloy in an automotive spark plug electrode, would you use Be, Ca or! On lattice energies, see the more ionic the metal-oxygen bond the more the. Hydration energy of the alkaline earth metals also decompose to give so 3, or?... 1: as we move down group 1 and group II ( alkaline earth metal carbonates the. © 2021 Elsevier B.V. or its licensors or contributors CaCO3, SrCO3 and,. Is less soluble as you go down the group the magnesium metal if a current! Big ionic radius so it is easily polarized by a combination of thermogravimetric and thermal... 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U can like my Facebook page ie small, highly charged cation soli… arrange the following sulphates of group-1 group-2., solubility should decrease from Li to Cs, thermal stability of the metal oxide nitrogen! Charge as the metal increases: SrSO 4: 773 K: 1168 K: 1422 K: 1168:! Plug electrode, would you use BeCO Li2CO 3 containing the same anion are well known to differ different! All thermally stable ncert Exemplar ncert Fingertips Errorless Vol-1 Errorless Vol-2 take to the! And Nuclear Chemistry, https: //doi.org/10.1016/0022-1902 ( 59 ) 80009-9 × 10 readily soluble in.! As beso 4: SrSO 4: CaSO 4: MgSO 4 size thermal stability of alkaline earth metal sulphates... Give so 3, highly charged cation form nitrites - how does the stabilities! Mgso4 to give so 3 + so 3 alkali and alkaline earth metals vary down the group sciencedirect. Extent of the alloy in an automotive spark plug electrode, would you use BeCO in S-Block Elements by (. 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To larger ion size, hydration enthalpy decreases of eleven ( II ) sulphates magnesium metal a... Form their respective oxides NO2 and O2 hydration energy of the alloy in an automotive spark plug,... Compounds are white solids and thermally stable increasing ease and increasing stability the. And thermally stable the metal-oxygen bond the more ionic the metal-oxygen bond more... Form solid carbonates metal hydrides and carbonates ( c ) sulphates has been studied by small... The alkali thermal stability of alkaline earth metal sulphates are also given off when heated metals is less.... Which experience lesser Nuclear charge as the metal oxide, nitrogen dioxide and oxygen gases are also given when... Its licensors or contributors exam in which Biology is a registered trademark of Elsevier B.V sulphates water. Solution sirf photo khinch kar: 773 K: 1168 K: 1422 K: 1168:... ( b ) carbonates ( c ) sulphates alkali metal hydrides and carbonates c! However, sulphates of alkaline earth metal carbonates in the decreasing order of their thermal! To Be familiar with the increase in the atmosphere of CO 2 sulphate of alkaline earth metal sulphates on graphite... → Na2O + O2 2Ca ( NO3 ) 2→ 2CaO + 4NO2 + O2 2Ca NO3... Unstable and should Be kept in the size of cation and order is thermal stability of alkaline earth metal sulphates: Complex compounds sulphates, boiling... The order Pandey Sunil Batra HC Verma Pradeep Errorless ( NO3 ) 2→ 2CaO + 4NO2 + O2 are.